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장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
73 Nov. 11th(Fri), 1:30 p.m.  #1323(E6-2. 1st fl.)  Dr. Keun Su Kim, POSTECH  Bandgap Engineering of Black Phosphorus
72 Nov. 16 (Wed), 4p.m.  #1323(E6-2. 1st fl.)  Dr. Heung-Sik Kim , University of Toronto  Realizing Haldane Model in Fe-based Honeycomb Ferromagnetic Insulators
71 Nov. 18th (Fri) 10:30 a.m.  #5318(5th fl.)  Dr. 최 순 원, Havard University  Non-equilibrium many-body spin dynamics in diamond
70 Nov. 1st (Tue), 10:30AM  #1323(E6-2 1st fl.)  Dr. Gadi Eisenstein, Technion  Time scale dependent dynamics in InAs/InP quantum dot gain media
69 Nov. 22th (Thur), 15:00  E6 Room(#1323)  Prof. Suprijadi Haryono  Experimental and Computational Study on Physical Properties based on Granular System file
68 NOV. 23 (Fri), 03:00 PM  E6-2. 2st fl. #2501  Prof. Sang-Jin Sin  Entanglement string and Spin Liquid with Holographic duality file
67 Nov. 24(Thu) 4p.m.  #1323(E6-2. 1st fl.)  Dr. Jai-Min Choi, Chonbuk National Univiersity  Harmonic oscillator physics with single atoms in a state-selective optical potential
66 Nov. 28 (Tue.), 4:00 PM  #1323 (E6-2. 1st fl.)  Samindranath Mitra, Editor at Physical Review Letters  Physics after the lab and the desk: Your work in PRL file
65 Nov. 29(Tue) 4p.m.  #1323(E6-2. 1st fl.)  Dr. SungBin Lee, KAIST  Symmetry Protected Kondo Metals and Their Phase Transitions
64 Nov. 3 (Fri.), 2:30 PM  #1323 (1st fl., E6-2.)  Dr. MinChul Lee(Department of Applied Physics, Kyung Hee Univ.)  Quantum Resistor-Capacitor Circuit with Majorana Edge States file
63 Nov. 3 (Fri.), 4:00 PM  #1323 (1st fl., E6-2.)  Dr. SungDae Ji (Max Planck POSTECH/Hshinchu Center (MPK))  Expedition to the Kitaev Quantum Spin Liquid: Hunting for Majorana fermions file
62 Nov. 8 (Wed.), 1:00 PM  #5318 (E6-2. 5th fl.)  Prof. Y. Matsuda Department of Physics, Kyoto University  “Emergent exotic quasiparticles in quantum spin liquids” file
61 Nov. 9 (Fri.), 02:30 PM  E6-2. 1st fl. #1323  Dr. Pilkyung Moon  Moiré superlattices – from twisted bilayer graphene to quasicrystal file
60 Nov. 9 (Fri.), 04:00 PM  E6-2. 1st fl. #1323  Dr. Donghun Lee  Quantum sensing and imaging with diamond defect centers for nano-scale spin physics file
59 November 1 (Thu.), 16:00 PM  #1323, E6-2  Dr. KyeoReh Lee  Direct holography from a single snapshot file
58 November 14 (Thu.), 16:00 PM  #1323, E6-2  Prof. Ji-Hun Kang  Semi-classical model of polariton propagation file
57 November 20 (Wed.), 4:00 PM  #5302, E6-2  Dr. Shigeyuki Ishida  Correlation between superconducting transition temperature and critical current density in irradiated iron-based superconductors file
56 November 21 (Wed.), 15:00 PM  #1323, E6-2  Prof. Seongshik Oh  Engineering topological quantum physics at the atomic scale file
55 November 28 (Thu.), 16:00 PM  #1323, E6-2  Prof. Kyung Taec Kim  Generation of coherent EUV emissions using ultrashort laser pulses file
54 November 29 (Thu.), 16:00 PM  #1323, E6-2  Dr. Kee suk Hong  양자 칸델라 실현을 위한 단일 광자 발생장치 개발 file