Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion
2017.04.26 13:51
장소 | E6-2. 1st fl. #1323 |
---|---|
일시 | Apr. 28 (Fri.), 02:30 PM |
연사 | Dr. JeongYoung Park Graduate School of EEWS, KAIST |
“Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion”
Dr. JeongYoung Park
Graduate School of EEWS, KAIST
Apr. 28 (Fri.), 02:30 PM
E6-2. 1st fl. #1323
Abstract:
A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance.
In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.
댓글 0
번호 | 일시 | 장소 | 연사 | 제목 |
---|---|---|---|---|
공지 | 2019/09/18 - 12/5 | Seminar Room #1323 | Prof. David Schuster and etc. | Fall 2019: Physics Seminar Serises |
공지 | 2019/09/02 - 12/09 | Seminar Room 1501 | 이호성 박사 (한국표준과학연구원) and etc. | Fall 2019: Physics Colloquium |
260 | May 13 (Fri.) 4 PM | E6. #1501(1st fl.) | Dr. Hosub Jin, Dept. of Physics, UNIST | Graphene analogue in (111)- BaBiO3 bilayer heterostructures for topological electronics |
259 | May 13 (Fri.), 1:30 PM | E6. #1501(1st fl.) | Dr. Young-Woo Son, Dept. of Physics, KIAS | Aperiodic crystals in low dimensions |
258 | 2018. 6. 22 10:00am ~ 11:50am | E6-6, Lecture Room 119 (1F) | Prof. Sang Bok Lee, Dept. of Chemistry and Biochemistry, Univ. of Maryland |
Success in Research Career
![]() |
257 | February 13th (Thur.), 16:30 PM | E6-6, #119 | Dr. Seyoon Kim(University of Wisconsin-Madison) |
Enhanced Light-Matter Interactions in Graphene with Noble Metal Plasmonic Structures
![]() |
256 | Apr. 08 (Fri.), 4:00 PM | E6-2. 5st fl. #1501 | Dr. Changyoung Kim, SEOUL NATIONAL UNIV. | Spectroscopic studies of iron-based superconductors : what have we learned? |
255 | Sep. 4 (Tue), 02:30 PM | E6-2. 2st fl. #2502 | Dr. Changmin Lee, MIT |
Ultrafast time- and angle-resolved photoemission spectroscopy (tr-ARPES) with extreme ultraviolet laser pulses
![]() |
254 | May. 3 (Fri), 11:00 AM | E6-2. 2st fl. #2502 | Prof. Changhee Sohn |
Exotic Magnetism
![]() |
253 | NOV. 23 (Fri), 03:00 PM | E6-2. 2st fl. #2501 | Prof. Sang-Jin Sin |
Entanglement string and Spin Liquid with Holographic duality
![]() |
252 | JAN. 7 (Mon), 03:00 PM | E6-2. 2st fl. #2501 | Dr. Byoung min Kang |
Many-Body Invariants for Multipoles in Higher-Order Topological Insulators
![]() |
251 | MAR. 26 (TUE), 0300 PM | E6-2. 2st fl. #2501 | Prof. Jung Hoon Han |
Consideration of thermal Hall effect in frustrated and un-frustrated quantum magnets
![]() |
250 | Jun. 18 (MON), 10:00 AM | E6-2. 2nd fl. #2502 | Dr. Thibault VOGT |
Rydberg electromagnetically induced transparency and microwave-to-optical conversion using Rydberg atoms
![]() |
249 | 2015/10/16, 4PM | E6-2. 2nd fl. #2501 | Prof. Yung-Fu Chen(Solid-state Laser Physics Laboratory,National Central University) | Fluctuations of entropy production in partially masked electric circuits |
248 | 2015/09/14, 2PM | E6-2. 2nd fl. #2501 | Dr. Hae Ja Lee ( Stanford University, SLAC ) | Ultrafast X-ray Studies on Dynamics Matter in Extreme Conditions |
247 | Jan.9 (Wed.), 04:00 PM | E6-2. 2nd fl. #2501 | Dr. Heung-Sik Kim |
Molecular Mott state in the deficient spinel GaV4S8
![]() |
246 | 2016/03/11 1:30 PM | E6-2. 1st fl. #1501 | Dr. Kwon Park | Topological phases of matter in nonequilibrium: Topology of the Wannier-Stark ladder |
245 | 2016/03/11 4 PM | E6-2. 1st fl. #1501 | Dr. Tae-Hwan KIM (POSTECH) | Jan. Switching handedness of of chiral solitons in Z4 topological insulators |
244 | Apr. 01 (Fri.) 2:30 PM | E6-2. 1st fl. #1501 | Dr. KICHEON KANG, Chonnam National University | Interference of single charged particles without a loop and dynamic nonlocality |
243 | Apr. 01 (Fri.) 4:15 PM | E6-2. 1st fl. #1501 | Dr. JONG SOO LIM, KIAS | Cotunneling drag effect in Coulomb-coupled quantum dots |
242 | Apr. 08 (Fri.), 13:30 PM | E6-2. 1st fl. #1501 | Dr. Yunkyu Bang, Chonnam National Univ. | Theoretical Overview of Iron-based superconductors and its future |
241 | Oct. 12 (Fri.), 02:30 PM | E6-2. 1st fl. #1323 | Dr. Daniel Kyungdeock Park |
Quantum Advantage in Learning Parity with Noise
![]() |