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장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
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공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
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140 2015/12/01, 4PM  E6-2, #1323  Dr. Yeong Kwan Kim(Lawrence Berkeley National Laboratory, USA)  Introducing extra dimensions to spectroscopic studies of advanced quantum materials
139 2015/11/10, 4PM  E6-2, #1323  Dr. Woosuk Bang (Physics division, Los Alamos National Laboratory)  Rapid heating of matter using high power lasers
138 October 16 (Tue.), 10:00 AM  #1323, E6-2  Dr. Won-Ki Cho  Capturing protein cluster dynamics and gene expression output in live cells file
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135 2016/03/11 4 PM  E6-2. 1st fl. #1501  Dr. Tae-Hwan KIM (POSTECH)  Jan. Switching handedness of of chiral solitons in Z4 topological insulators
134 2015/11/28, 10AM  E6-2, #1323  Dr. Suyong Jung (Korea Research Institute of Standards and Science)  Electron Tunneling Spectroscopy of Single and Bilayer Graphene with Hexagonal Boron Nitride as Tunneling Barrier
133 May 1 (Wed), 4:00 PM  #1323, E6-2  Dr. Sungkyun Choi  Raman and x-ray scattering study on correlated electron systems: two case examples file
132 April 13 (Fri.), 10am  #1323 (E6-2, 1st fl.)  Dr. Sungkun Hong  Quantum meets Mechanics: from Quantum Information to Fundamental Research file
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130 Nov. 29(Tue) 4p.m.  #1323(E6-2. 1st fl.)  Dr. SungBin Lee, KAIST  Symmetry Protected Kondo Metals and Their Phase Transitions
129 Oct. 07 (Fri), 1:30 PM  E6-2. #1323(1st fl.)  Dr. Suk Bum Chung, IBS-CCES , Seoul National University  “Symmetry and topology in transition metal dichalcogenide?”
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127 November 5 (Tue.), 4:00 PM  #1323, E6-2  Dr. Shik Shin  Study on nanomaterials by the development of ultrahigh resolution laser-photoelectron microscopy (PEEM) file
126 November 20 (Wed.), 4:00 PM  #5302, E6-2  Dr. Shigeyuki Ishida  Correlation between superconducting transition temperature and critical current density in irradiated iron-based superconductors file
125 October 31 (Thu.), 10:00am  #1323 (E6-2, 1st fl.)  Dr. Seung-Sup Lee  Kondo meets Hubbard: Impurity physics for correlated lattices file
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