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장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
170 August. 16th (Fri), 14:00  E6 Room(#1323)  Jinxing Zhang  Multiferroic and Magnetoelectric Effects by Tailoring Interfacial Chemistry and Physics in Correlated Oxides file
169 May. 8th (Wed), 16:00  E6 Room(#1323)  Jieun Lee  Imaging valley dependent electron transport in 2D semiconductors file
168 May. 8th (Wed), 16:00  E6 Room(#1323)  Jieun Lee  Imaging valley dependent electron transport in 2D semiconductors file
167 June 27 (Thu), 2:00 PM  #2502, E6-2  Hyun-Yong Lee  Gapless Kitaev Spin Liquid to Loop and String Gases file
166 Jun. 16 (Thu) 4PM  #1323(E6-2, 1st fl.)  Hyochul Kim, Samsung Advanced Institute of Technology  Quantum information processing using quantum dots and photonic crystal cavities
165 August. 1st (Thu), 14:00  E6 Room(#1323)  Hyeok Yoon  Low-density Superconductivity in SrTiO3 Probed by Planar Tunneling Spectroscopy file
164 August 27 (Tue.), 4:00PM  Rm. 1323, E6  Hiroshi Eisaki  Critical current properties of Fe-based superconductors file
163 January 17 (Fri), 4:00 PM  #1323, E6-2  Hiroki Ikegami  Symmetry Breaking and Topology in Superfluid 3He file
162 September 26 (Thu.), 16:00 PM  #1323, E6-2  Han Seb Moon  Entanglement Swapping with Autonomous Polarization-Entangled Photon-Pairs from Warm Atomic Ensemble file
161 December 27(Fri.), 15:00  E6-2,#5318  Han Gyeol Suh  The superconducting order parameter puzzle of Sr2RuO4 file
160 Dec 27 (Fri), 3:00 PM  #5318, E6-2  Han Gyeol Suh  The superconducting order parameter puzzle of Sr2RuO4 file
159 Nov. 18th (Fri) 10:30 a.m.  #5318(5th fl.)  Dr. 최 순 원, Havard University  Non-equilibrium many-body spin dynamics in diamond
158 Oct. 27th(Thu) 4PM  #1323(E6-2)  Dr. 이 강 희, KAIST, Mechnical Engineering  Terahertz Metal Optics
157 June 28 (Fri.), 13:30 PM  #1323, E6-2  Dr. Yusuke Kozuka  Magnetic domains and domain wall conduction in pyrochlore iridate thin films and heterostructures file
156 Apr. 08 (Fri.), 13:30 PM  E6-2. 1st fl. #1501  Dr. Yunkyu Bang, Chonnam National Univ.  Theoretical Overview of Iron-based superconductors and its future
155 Sep. 26 (Tue.), 11AM  #1323 (E6-2. 1st fl.)  Dr. Yukiaki Ishida / ISSP, University of Tokyo  Time-resolved ARPES study of Dirac and topological materials
154 Nov. 1 (Fri.), 02:30 PM  E6-2. 1st fl. #1323  Dr. YoungWook Kim  Squeezing the best out of 2D materials file
153 Apr. 19 (Fri.), 02:30 PM  E6-2. 1st fl. #1323  Dr. YoungWoo Nam  A family of finite-temperature electronic phase transitions in graphene multilayers file
152 2015/11/06, 4:30 PM  E6-2, #5318  Dr. Youngkuk Kim (University of Pennsylvania)  Topological Dirac line nodes in centrosymmetric semimetals
151 Mar. 16 (Fri.), 04:0 PM  E6-2. 1st fl. #1323  Dr. YoungDuck Kim  Van der Waals Heterostructures from Quantum Transport to Ultrafast Optoelectronics file