visual
visual

세미나

  • HOME
  • >
  • 소식
  • >
  • 세미나
장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
245 November 21 (Wed.), 15:00 PM  #1323, E6-2  Prof. Seongshik Oh  Engineering topological quantum physics at the atomic scale file
244 November 5 (Tue.), 4:00 PM  #1323, E6-2  Dr. Shik Shin  Study on nanomaterials by the development of ultrahigh resolution laser-photoelectron microscopy (PEEM) file
243 June 27 (Wed.), 13:30 PM  #1323, E6-2  Dr. Jung Sik Park  Magnetic reversal of artificial spin ice file
242 November 28 (Thu.), 16:00 PM  #1323, E6-2  Prof. Kyung Taec Kim  Generation of coherent EUV emissions using ultrashort laser pulses file
241 November 14 (Thu.), 16:00 PM  #1323, E6-2  Prof. Ji-Hun Kang  Semi-classical model of polariton propagation file
240 April 26 (Fri.), 4:00 PM  #1323, E6-2  Dr. Soonwon Choi  Robust Quantum Metrology using Strongly Interacting Spin Ensembles and Quantum Convolutional Neural Network file
239 May 1 (Wed), 4:00 PM  #1323, E6-2  Dr. Sungkyun Choi  Raman and x-ray scattering study on correlated electron systems: two case examples file
238 December 13 (Fri.), 1:30-4:30 PM  #1323, E6-2    Biophysics Mini-symposium at KAIST file
237 June 22 (Fri.), 04:00 PM  #1323, E6-2  Dr. Daniel Sando  Tuning functional properties of BiFeO3 films using strain and growth chemistry file
236 June 22 (Fri.), 04:00 PM  #1323, E6-2  Dr. Daniel Sando  Tuning functional properties of BiFeO3 films using strain and growth chemistry file
235 November 29 (Thu.), 16:00 PM  #1323, E6-2  Dr. Kee suk Hong  양자 칸델라 실현을 위한 단일 광자 발생장치 개발 file
234 November 7 (Thu.), 16:00 PM  #1323, E6-2  Prof. Je-Hyung Kim  Integrated quantum photonics with solid-state quantum emitters file
233 December 3 (Tue.), 4:00 PM  #1323, E6-2  Dr. Jong Mok Ok  Toward Quantum Materials with Correlated Oxides file
232 December 18 (Tue.), 4:00 PM  #1323, E6-2  Prof. Shin-ichi Uchida  Road to Higher Tc Superconductivity file
231 May 29 (Tue.), 04:00 PM  #1323, E6-2  Prof. Jae-Won Jang  Investigation on metal nanostructure/semiconductor junction and its applications file
230 February 20 (Thu), 4:00 PM  #1323, E6-2  Seunghyun Khim  Unconventional superconductivity in the locally non-centrosymmetric heavy-fermion CeRh2As2 file
229 May 2 (Thu.), 4:00 PM  #1323, E6-2  Prof. Joon Ik Jang  Anomalous optical properties of halide perovskites file
228 June 28 (Fri.), 13:30 PM  #1323, E6-2  Dr. Yusuke Kozuka  Magnetic domains and domain wall conduction in pyrochlore iridate thin films and heterostructures file
227 October 18 (Thu.), 10:00 AM  #1323, E6-2  Dr. Duyoung Min  Understanding membrane protein folding using single-molecule force techniques file
226 July 9 (Mon.), 14:00 PM  #1323, E6-2  Prof. Cesar A. Hidalgo, MediaLab, MIT  The principles of collective learning file