visual
visual

세미나

  • HOME
  • >
  • 소식
  • >
  • 세미나
장소 #1323, E6-2 
일시 June 22 (Fri.), 04:00 PM 
연사 Dr. Daniel Sando 

Physics Seminar

 

 

Tuning functional properties of BiFeO3films using strain and growth chemistry

 

Dr. Daniel Sando

Univ. of New South Wales, Sydney

 

June 22 (Fri.), 04:00 PM

#1323, E6-2

 

Abstract:

Multiferroics – materials with coexisting ferroic orders such as ferroelectricity and (anti)-ferromagnetism – are presently under intense study by virtue of their promise in next-generation data storage devices. Bismuth ferrite (BiFeO3– BFO) is one of the very few that orders above room temperature. In the bulk, BFO is rhombohedral (R), and in thin films [1] its properties are sensitive to strain [2,3]. The discovery of the epitaxially-stabilized “super tetragonal phase” of BFO (T-BFO) [4] incited a flurry of research activity focused on understanding the phase transition and its possible functionalities [5]. T-BFO is also multiferroic, with large ferroelectric polarization and antiferromagnetic order [4], and the strain relaxation-induced T/R phase mixtures and their exceptional piezoelectric responses [6] continue to intrigue and motivate researchers. A particularly important characteristic of this phase mixture is the interconversion between the R,T phases with an applied electric field [6]. Since the oxygen configuration of the R and T polymorphs is different [5], the electronic, magnetic, and optical properties can thus be dynamically modulated. An additional rather crucial (and thus far underexplored) aspect of mixed R/T BFO is the role of chemistryin the formation of the metastable T-phase. Since T-BFO is typically fabricated by pulsed laser deposition, growth parameters can be used as a strong handle to tailor film properties and functionalities.

Here I will describe our work on understanding the influence of strain and growth conditions on the optical, magnetic, and ferroelectric properties of BFO films. I will also show that by precisely controlling fabrication conditions, the formation of the mixed R/T phases in BFO films can be completely suppressed for thicknesses above 70 nm. Such an intriguing result is useful for applications where thicker pure T-BFO films are needed, such as for measuring the expected giant polarization, or for precisely controlling the proportions of the various phases. Finally, through analysis of a large set of epitaxial films, it will be shown that the optical band gap of BFO is rather insensitive to a host of growth and processing parameters [7]. Combined with the numerous other functionalities of this material, one can envisage multifunctional devices, for example, that harvest mechanical and solar energy, or to enhance magnetoelectric coupling at these multiferroic phase boundaries.

References

[1] Sando et al., J. Phys: Condens. Matt. 26, 473201 (2014). 

[2] Infante et al., PRL 105, 057601 (2010). 

[3] Sando et al., Nat. Mater. 12, 641 (2013). 

[4] Bea et al., PRL 102, 217603 (2009). 

[5] Sando et al., Appl. Phys. Rev. 3, 011106 (2016). 

[6] Zeches et al., Science 326, 977 (2009). 

[7] Sando et al., Adv. Opt Mater. 6, 1700836 (2018).

 

 

 Department of Physics, KAIST

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
72 5월 17일(화), 11:00 ~ 12:00  창의학습관(E11), 406호  방준혁 박사(Korea Basic Science Institute, KBSI)  The CERN Resonant WISP Search: Development, Results and Lesson-Learned
71 4월 18일(월), 15:30~  KI빌딩(E4), 강의실 B501 (5F)  Prof. Robert A. DiStasio Jr. (Cornell University)  First Principles Approaches for Intermolecular Interactions: From Gas-Phase Dimers to Liquid Water and Molecular Crystal Polymorphism file
70 4pm, Sep. 21 (Wed.  E6-2. #2502(2nd fl.)  Dr. Henrik Johannesson , University of Gothenburg (Sweden) and Beijing Computational Science Research Center (China)  Entanglement probe of two-impurity Kondo physics
69 3 PM, 12 Jun (Wed), 2019  Rm# 1323, E6-2  Dr. Minyoung You  The relation between free and interacting fermionic SPT phases file
68 2019. 8. 22 4PM & 8. 23 3PM  #1323, E6-2  Prof. Andrew N Cleland  Physics and Applications in Nanoelectronics and Nonomechanics file
67 2019. 7. 16(화)  Rm. 1323 (E6-2)  Prof. Sidney Nagel  2019 Physics Distinguished Lecture file
66 2018년 9월 7일 (금), 3PM  학술문화관 (E9), 2층 양승택 오디토리움  Prof. Martin Head-Gordon, UC Berkeley  Recent developments in density functional theory: From new functionals to the nature of the chemical bond file
65 2018. 6. 22 10:00am ~ 11:50am  E6-6, Lecture Room 119 (1F)  Prof. Sang Bok Lee, Dept. of Chemistry and Biochemistry, Univ. of Maryland  Success in Research Career file
64 2017/03/21 - 06/08  Seminar Room 1323  조길영 박사(KAIST) 외  Spring 2017: Physics Seminar Serises file
63 2017/03/06 - 05/29  Seminar Room 1501  이종봉 박사 (POSTECH) 외  Spring 2017: Physics Colloquium file
62 2017.1.9(Mon), 4PM  Lecture Hall, College of Natural Sciences [#1501,E6-2]  Prof. John Michael Kosterlitz, Brown University  Topological Defects and Phase Transitions" file
61 2016/1/26, 2PM  E6-2, #1323  Dr. Sergei V. Kalinin (Center for Nanophase Materials Sciences, Oak Ridge National Laboratory)  Electrochemistry on Nano- and Atomic Levels: Scanning Probe Microscopy Meets Deep Data
60 2016/1/11, 4PM  E6-2, #1323  Dr. B.J.Kim (Max Planck Institute for Solid State Research)  Mott Physics in the Strong Spin-Orbit Coupling Regime
59 2016/09/29-12/13  E6-2, #1323  Sangyoon Han 외  2016 Fall, Physics Seminar Serises file
58 2016/09/05-12/12 4PM  Natual Scien Bldg.(E6)m #1501  Yeong Kwan Kim 외  Physics Colloquium : 2016 Fall file
57 2016/03/11-06/09  E6-2, 1501 외  박권(KAIS) 외  Physics Seminar Serises : 2016 Spring file
56 2016/03/11 4 PM  E6-2. 1st fl. #1501  Dr. Tae-Hwan KIM (POSTECH)  Jan. Switching handedness of of chiral solitons in Z4 topological insulators
55 2016/03/11 1:30 PM  E6-2. 1st fl. #1501  Dr. Kwon Park  Topological phases of matter in nonequilibrium: Topology of the Wannier-Stark ladder