visual
visual

세미나

  • HOME
  • >
  • 소식
  • >
  • 세미나
장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
120 DEC. 27 (Thu), 04:00 PM  E6-2. 1st fl. #1323  Prof. Na Young Kim  Quantum Innovation (QuIN) Laboratory file
119 Dec. 26 (Wed.), 04:00 PM  E6-2. 1st fl. #1323  Dr. Isaac H. Kim  Brane-like defect in 3D toric code file
118 DEC. 26 (Wed), 04:00 PM  E6-1. 3rd fl. #3434  Y. Kim, A. Go, K. Hwang and E.-G. Moon  Informal Workshop on Topology and Correlation file
117 DEC. 16~18 (Sun~Tue)  E6-2. 1st fl. #1323  Prof. Keisuke Totsuka  Lectures on 2d Conformal Field Theory file
116 Dec. 15 (Fri.), 9:20 AM  E6-2, Lecture Room #1323  Prof. Jhinhwan Lee 외 9명  Workshop on Magnetism in Unconventional Superconductors 개최 file
115 Dec. 13-14(Wed.-Thu.) 13:30 PM  자연과학동 대형강의실 (1501호)  장기주 교수 외 9명  KAIST-KIAS Joint Workshop in Theoretical Sciences 개최 file
114 Dec. 12th (Mon)  1:30p.m. #1323(E6-2. 1st fl.)  Dongjoon Song , AIST  “Possible symmetry in the phase diagrams of electron- & hole-doped cuprate high-Tc superconductors”
113 DEC. 11 (Tue), 04:00 PM  E6-2. 1st fl. #1323  Prof. Hiroshi Shinaoka  Natural compact representation of Matsubara Green’s functions: applications to analytic continuation and quantum many-body simulations file
112 August. 6th (TUE), 14:00  E6 Room(#1323)  Kanghyun Chu  Visualization of in-plane piezoresponse vector fields file
111 August. 1st (Thu), 14:00  E6 Room(#1323)  Hyeok Yoon  Low-density Superconductivity in SrTiO3 Probed by Planar Tunneling Spectroscopy file
110 August. 16th (Fri), 14:00  E6 Room(#1323)  Jinxing Zhang  Multiferroic and Magnetoelectric Effects by Tailoring Interfacial Chemistry and Physics in Correlated Oxides file
109 August. 14th (Wed.), 4:00PM,  Rm. 1323, E6  Prof. Nicolas Treps  Quantum Optics, at the heart of quantum metrology and quantum information file
108 August 27 (Tue.), 4:00PM  Rm. 1323, E6  Hiroshi Eisaki  Critical current properties of Fe-based superconductors file
107 August 1, 2018 at 11:00AM  양분순 빌딩 (E16-1) 207호  이대열 교수, 예일대 석좌교수  Future of AI: Is the brain a computer? file
106 Aug. 4, 2016 (Thu.), 2:30 pm  KAIST Natural Science Building (E6-5), EDU 3.0 Room(1st fl.)  Prof. Argyris Nicolaidis  Relational Logic (with applications to Quantum Mechanics, String Theory, Cosmology, Neutrino Oscillations, Statistical Mechanics)
105 AUG. 31 (Thu.), 2 PM  #5318(E6-2. 5th fl.)  Prof. Hiroaki Ishizuka (The University of Tokyo)  “Berry phase and nonlinear response: photocurrent in noncentrosymmetric insulators and Weyl semimetals” file
104 Aug. 16 (Wed.), 4 PM  #1322 (E6-2. 1st fl.)  Prof. Noejung Park (UNIST)  Phonon-driven spin-Floquet valleytro-magnetism file
103 April 6, 2017 (Thu), 4:00 pm  IBS CAPP seminar room, Creation Hall (3F), KAIST Munji Campus  Prof. Youngjoon Kwon (Yonsei University)  For whom the Belle tolls
102 April 6, 2016 (Wed), 3:30 PM  E6-2, RM #1323  Dr. Andrei Matlashov (Los Alamos National Laboratory)  Superconducting Quantum Interference Devices for Precision Detection
101 April 6 (Fri.), 10:00 AM  #2502, E6  박채연 박사  Entanglement and thermalization in many-body systems: recent progress file