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장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
108 April 26 (Tue), 4PM  #1323(1st Floor. E6-2)  Dr. Myung-Ho Bae, Korea Research Institute of Standards and Science  Transport spectroscopy for electronic bands in carbon-based nanomaterials with weak-bond contacts
107 3 PM, 12 Jun (Wed), 2019  Rm# 1323, E6-2  Dr. Minyoung You  The relation between free and interacting fermionic SPT phases file
106 Sep. 29 (Thu), 4:00 PM  E6-2. #2501(2nd fl.)  Dr. Minu Kim, Institute for Basic Science, Seoul National University  Exploring the phase diagram of BaBiO3: epic voyage of just another bad trip?
105 Apr. 28 (Fri.), 04:00 PM  #1323 (E6-2. 1st fl.)  Dr. Minkyung Jung Research Institute, DGIST  Carbon nanotubes coupled to superconducting impedance matching circuits
104 July 30 (Tue), 4:00 PM  #1323, E6-2  Dr. Mingu Kang  Dirac fermions and flat bands in correlated kagome metals file
103 Nov. 3 (Fri.), 2:30 PM  #1323 (1st fl., E6-2.)  Dr. MinChul Lee(Department of Applied Physics, Kyung Hee Univ.)  Quantum Resistor-Capacitor Circuit with Majorana Edge States file
102 Sep. 10 (Tue.), 03:00 PM  E6-2. 1st fl. #1323  Dr. Mikhail Kiselev  Two-Stage Kondo Effect file
101 Feb. 1 (Wed.), 2p.m.  #1323(E6-2. 1st fl.)  Dr. Michihisa Yamamoto, Department of Applied Physics, The University of Tokyo  Quantum electron optics using flying electrons
100 2015/11/23, 1:30PM  E6-2, #1323  Dr. Michael Park (Stanford University)  What's Beyond the Standard Model? Lessons from Run I and what might come in Run II
99 Jul. 08 (Fri.) 11:00 AM  #1323(E6-2. 1st fl.)  Dr. Michael Lawler(Binghampton Univ. / Cornell Univ.)  Isostatic magnetism
98 May 19, 2016 (Thur.) 3PM  May 19, 2016 (Thur.) 3PM,  Dr. Michael Betz, CERN  The CERN Resonant WISP Search: Development, Results and Lesson-Learned
97 2015/10/15, 10AM  E6-2, 5th fl. #5318  Dr. Mark D. Bird (Florida State University)  Development of Large-Bore, High Field Magnets at the NHMFL
96 Mar. 24 (Fri.), 2:30 PM  #1323 (1st fl. E6-2).  Dr. MahnSoo Choi  Topological Dynamics
95 October 26 (Fri.), 4:00 PM  #1323, E6-2  Dr. Kyusung Hwang  Coexisting triple-point and nodal-line topological magnons and thermal Hall effect in pyrochlore iridates file
94 2015/07/16, 4PM  E6-2, 1318  Dr. Kyunghan Hong(MIT)  Next-generation ultrafast laser technology for nonlinear optics and strong-field physics
93 November 1 (Thu.), 16:00 PM  #1323, E6-2  Dr. KyeoReh Lee  Direct holography from a single snapshot file
92 2016/03/11 1:30 PM  E6-2. 1st fl. #1501  Dr. Kwon Park  Topological phases of matter in nonequilibrium: Topology of the Wannier-Stark ladder
91 2015/12/11, 1:30PM  E6-2, #1323  Dr. KwangYong Choi  (Chung-Ang University)  Quantum spin liquid in the 1/3 depleted triangular lattice Ba3(Ru1-xIrx)Ti2O9
90 Dec. 9(Fri), 4p.m.  #1323(E6-2. 1st fl.  Dr. Kun Woo Kim, KIAS  Shift Charge and Spin Photocurrents in Dirac Surface States of Topological Insulator
89 May. 11 (Fri.), 02:30 PM  E6-2. 1st fl. #1323  Dr. Kun Woo Kim  Disordered Floquet topological insulators file