visual
visual

세미나

  • HOME
  • >
  • 소식
  • >
  • 세미나
장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
248 July 30 (Tue), 4:00 PM  #1323, E6-2  Dr. Mingu Kang  Dirac fermions and flat bands in correlated kagome metals file
247 July 21 - August 2  E6-2,# 5318  Junmou Chen/Thomas Flacke/Kaoru Hagiwara/Junichi Kanzaki/Chris Kelso/Jeong Han Kim/Kyoungchul Kong/Gabriel Lee/Hye-Sung Lee/Ian Lewis  Challenges and Opportunities in Theoretical Particle Physics 2019 file
246 July 25(Thur.),4:00PM  E6-2, #1323  Prof.Bohm-Jung Yang  Band topology of twisted bilayer graphene file
245 2019. 7. 16(화)  Rm. 1323 (E6-2)  Prof. Sidney Nagel  2019 Physics Distinguished Lecture file
244 July 8(Mon), 14:00  E6, #1322  T. L. M. Guedes (Univ. of Konstanz)  Ultrabroadband squeezed pulses and their relation to relativity file
243 Jun 28, 14:00  E6-2, #1322  Dr. Bongjae Kim, Dr. Sooran Kim, Dr. Jeongwoon Hwang  1st Research-exchange meeting of computational material physics file
242 June 27 (Thu), 2:00 PM  #2502, E6-2  Hyun-Yong Lee  Gapless Kitaev Spin Liquid to Loop and String Gases file
241 June 28 (Fri.), 13:30 PM  #1323, E6-2  Dr. Yusuke Kozuka  Magnetic domains and domain wall conduction in pyrochlore iridate thin films and heterostructures file
240 Jun 24 (Mon) 11:00  E6-2, #1323  Dr. Henning Schomerus  Topological photonic anomalies file
239 Jul 3rd, 2019 (Wed)  E6-2, 2501  Kyung Soo Choi  Many-body quantum electrodynamis (QED) with atoms and photons: A new platform for quantum optics" file
238 July 10 (Wed.), 04:00 PM-  Academic Cltural Complex (E9) 5층 스카이라운지  Prof. Sidney Nagel/Young-Kee Kim  Public Lectures file
237 June 17 (Mon.), 10:30 AM  #1323, E6-2  Dr. See-Hun Yang  Chiral Spintronics file
236 3 PM, 12 Jun (Wed), 2019  Rm# 1323, E6-2  Dr. Minyoung You  The relation between free and interacting fermionic SPT phases file
235 June 4 (Tue.), 5:00 PM  #1323, E6-2  Prof. Minsu Kim  Stochastic nature of bacterial eradication using antibiotics file
234 May 30 (Thu.), 16:00 PM  #1323, E6-2  Prof. Chang-Hee Cho  Tuning the excitonic properties of semiconductors with light-matter interactions file
233 May 24 (Fri.), 16:00 PM  #1323, E6-2  Prof. Soonjae Moon  Infrared spectroscopy study on metal-insulator transitions in layered perovskite iridates file
232 May 31 (Fri.), 11:00 AM  #1323, E6-2  Prof. Guido Burkard  Cavity QED with Spin Qubits file
231 May 21 (Tue.), 4:00 PM  #5318, E6-2  임준원 박사  Classification of flat bands according to the band-crossing singularity of Bloch wave functions file
230 May 9 (Thu.), 16:00 PM  #1323, E6-2  Prof. Kwang Geol Lee  Quantum Optical Sensing Using Single Photons And Single Photon Emission from Single Emitters file
229 May. 8th (Wed), 16:00  E6 Room(#1323)  Jieun Lee  Imaging valley dependent electron transport in 2D semiconductors file