visual
visual

세미나

  • HOME
  • >
  • 소식
  • >
  • 세미나
장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
54 September 26 (Thu.), 16:00 PM  #1323, E6-2  Han Seb Moon  Entanglement Swapping with Autonomous Polarization-Entangled Photon-Pairs from Warm Atomic Ensemble file
53 October 15 (Tue.), 16:00 PM  #1323, E6-2  Prof. Pilkyung Moon  Moiré superlattices and graphene quasicrystal file
52 October 17 (Thu.), 16:00 PM  #1323, E6-2  Prof. Namkyoo Park  Top down manipulation of Waves : From Metamaterials, Correlated Disorder, Quantum Analogy, to Digital Processing file
51 Oct. 25 (Fri), 15:00 ~  #1323, E6-2  Daesu Lee,Junwoo Son,MyungJoon Han ,Siheon Ryee,Eun-Gook Moon  Physics Seminar file
50 October 29 (Tue.), 14:30 PM  #1323, E6-2  Prof. Jörg Wrachtrup  Quantum sensing file
49 November 5 (Tue.), 4:00 PM  #1323, E6-2  Dr. Shik Shin  Study on nanomaterials by the development of ultrahigh resolution laser-photoelectron microscopy (PEEM) file
48 November 7 (Thu.), 16:00 PM  #1323, E6-2  Prof. Je-Hyung Kim  Integrated quantum photonics with solid-state quantum emitters file
47 January 17 (Fri), 4:00 PM  #1323, E6-2  Hiroki Ikegami  Symmetry Breaking and Topology in Superfluid 3He file
46 February 20 (Thu), 4:00 PM  #1323, E6-2  Seunghyun Khim  Unconventional superconductivity in the locally non-centrosymmetric heavy-fermion CeRh2As2 file
45 Mar. 2nd (Thu), 4:00 p.m  #1323(E6-2. 1st fl.)  Dr. Jonathan Denlinger, Lawrence Berkeley National Lab  “Progress in the comparison of ARPES to DMFT for d and f strongly correlated electron systems”
44 Apr. 19(Tue.), 2PM  #1323(E6-2. 1st fl.)  Prof. Mark Koepke, Department of Physics and Astronomy, West Virginia University, USA  Nonlocal collisional electron transport in partially ionized plasma generation, structure, and stability
43 Jul. 08 (Fri.) 11:00 AM  #1323(E6-2. 1st fl.)  Dr. Michael Lawler(Binghampton Univ. / Cornell Univ.)  Isostatic magnetism
42 Jul. 07 (Thu.) 2PM  #1323(E6-2. 1st fl.)  Dr. Eun Ah Kim, CORNELL UNIV.  Let there be topological superconductors
41 Jul. 08 (Fri.) 2PM  #1323(E6-2. 1st fl.)  Dr. Junhyun Lee, Harvard University  Electronic quasiparticles in the quantum dimer model
40 Jul. 28 (Thu.) 4PM  #1323(E6-2. 1st fl.)  Prof. Johannes Pollanen, Jerry Cowen Chair of Experimental Physics at Michigan State University  Low Dimensional Electrons: On the Road to Hybrid Quantum Systems
39 Nov. 11th(Fri), 1:30 p.m.  #1323(E6-2. 1st fl.)  Dr. Keun Su Kim, POSTECH  Bandgap Engineering of Black Phosphorus
38 Nov. 11th (Fri), 4 p.m.  #1323(E6-2. 1st fl.)  Dr. Bohm-Jung Yang, SNU  Dirac fermions in condensed matters
37 Nov. 16 (Wed), 4p.m.  #1323(E6-2. 1st fl.)  Dr. Heung-Sik Kim , University of Toronto  Realizing Haldane Model in Fe-based Honeycomb Ferromagnetic Insulators
36 Nov. 24(Thu) 4p.m.  #1323(E6-2. 1st fl.)  Dr. Jai-Min Choi, Chonbuk National Univiersity  Harmonic oscillator physics with single atoms in a state-selective optical potential
35 Nov. 29(Tue) 4p.m.  #1323(E6-2. 1st fl.)  Dr. SungBin Lee, KAIST  Symmetry Protected Kondo Metals and Their Phase Transitions