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장소 E6-2. 1st fl. #1323 
일시 Apr. 28 (Fri.), 02:30 PM 
연사 Dr. JeongYoung Park Graduate School of EEWS, KAIST 

 

Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion

 

Dr. JeongYoung Park

Graduate School of EEWS, KAIST

Apr. 28 (Fri.), 02:30 PM

E6-2. 1st fl. #1323

 

 

Abstract: 

A pulse of high kinetic energy electrons (1–3 eV) in metals can be generated after surface exposure to external energy, such as the absorption of light or exothermic chemical processes. These energetic electrons are not at thermal equilibrium with the metal atoms and are called ‘‘hot electrons’’. The detection of hot electrons and understanding the correlation between hot electron generation and surface phenomena are challenging questions in the surface science and catalysis community. Hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) appears to be correlated with localized surface plasmon resonance. 

In this talk, I will show strategy to quantify the non-adiabatic energy transfer and detect hot electron flux during the elementary steps of the energy conversion process and catalytic reaction processes occurring at both of solid-gas and solid-liquid interfaces. To detect and utilize the hot electron flows, the nanodiodes consisting of metal catalyst film, semiconductor layers, and Ohmic contact pads were constructed It was shown that the chemicurrent or hot electron flows were well correlated with the turnover rate of CO oxidation or hydrogen oxidation separately measured by gas chromatography, suggesting the intrinsic relation between catalytic reaction and hot electron generation. We show a novel scheme of graphene catalytic nanodiode composed of a Pt NPs array on graphene/TiO2 Schottky nanodiode, which allows detection of hot electron flows induced by hydrogen oxidation on Pt NPs. By analyzing the correlation between the turnover rate (catalytic activity) and hot electron current (chemicurrent) measured on the graphene catalytic nanodiodes, we demonstrate that the catalytic nanodiodes utilizing a single graphene layer for electrical connection of Pt NPs are beneficial for the detection of hot electrons due to not only atomically thin nature of graphene but also reducing the height of the potential barrier existing at the Pt NPs/graphene interface. I will show that hot electron flow generated on a gold thin film by photon absorption (or internal photoemission) is amplified by localized surface plasmon resonance. Finally, The effect of surface plasmons on the catalytic and photocatalytic activity on metal–oxide hybrid nanocatalysts is also highlighted. These phenomena imply the efficient energy conversion from the photon energy to the chemical energy, with the potential application of hot electron-based photocatalytic devices.

 

 

 

번호 일시 장소 연사 제목
공지 2019/09/18 - 12/5  Seminar Room #1323  Prof. David Schuster and etc.  Fall 2019: Physics Seminar Serises
공지 2019/09/02 - 12/09  Seminar Room 1501  이호성 박사 (한국표준과학연구원) and etc.  Fall 2019: Physics Colloquium
104 Dec. 15 (Fri.), 9:20 AM  E6-2, Lecture Room #1323  Prof. Jhinhwan Lee 외 9명  Workshop on Magnetism in Unconventional Superconductors 개최 file
103 April 6, 2016 (Wed), 3:30 PM  E6-2, RM #1323  Dr. Andrei Matlashov (Los Alamos National Laboratory)  Superconducting Quantum Interference Devices for Precision Detection
102 July 21 - August 2  E6-2,# 5318  Junmou Chen/Thomas Flacke/Kaoru Hagiwara/Junichi Kanzaki/Chris Kelso/Jeong Han Kim/Kyoungchul Kong/Gabriel Lee/Hye-Sung Lee/Ian Lewis  Challenges and Opportunities in Theoretical Particle Physics 2019 file
101 2015/07/15, 2PM  E6-2,1323  Dr. Se Young Park(Rutgers Univ.)  Electronic and optical properties of titanate-based oxide superlattices
100 May 11 (Wed.), 4 PM  E6-2. #1323(1st fl.)  Dr. Bumjoon Kim, Max Planck Institute for Solid State Research  The quest for novel high-temperature superconductors---Prospects and progress in iridates
99 May 24 (Tue) 4 PM  E6-2. #1323(1st fl.)  Dr. Euyheon Hwang, SKKU Advanced Institute of Nanotechnology, Sung Kyung Kwan University  Electronic and magnetic properties of 2D transition-metal thiophosphates and tunability of magnetic order with carrier density
98 Oct. 07 (Fri), 1:30 PM  E6-2. #1323(1st fl.)  Dr. Suk Bum Chung, IBS-CCES , Seoul National University  “Symmetry and topology in transition metal dichalcogenide?”
97 Oct. 07 (Fri), 4:00 PM  E6-2. #1323(1st fl.)  Dr. Choong Hyun Kim,IBS-CCES, Seoul National University  “Tilt engineering of 4d and 5d transition metal oxides?”
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91 2015/09/07, 3PM  E6-2. 1st fl. #1318  Dr. Jasbinder Sanghera (U.S. Naval Research Laboratory (NRL))  Advanced Optical Materials and Devices at NRL
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» Apr. 28 (Fri.), 02:30 PM  E6-2. 1st fl. #1323  Dr. JeongYoung Park Graduate School of EEWS, KAIST  Hot electron generation at surfaces and its impact to catalysis and renewable energy conversion
86 Apr. 12 (Tue.), 4 PM  E6-2. 1st fl. #1323  Dr. Jeehoon Kim, POSTECH  Confinement of Superconducting Vortices in Magnetic Force Microscopy
85 Oct. 18 (Tue.), 3PM  E6-2. 1st fl. #1323  Dr. JunHo Suh, Korea Research Institute of Standards and Science  “Hybrid quantum systems with mechanical oscillators”